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1 article(s) from Gaikwad, Sudhakar

Selective detection of DABCO using a supramolecular interconversion as fluorescence reporter

Indrajit Paul,
Debabrata Samanta,
Sudhakar Gaikwad and
Michael Schmittel

Beilstein J. Org. Chem. 2019, 15, 1371–1378, doi:10.3762/bjoc.15.137

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Graphical Abstract

Figure 1: Molecular structures of ligands 1, 2, 3, and 4 and of the resulting products, i.e., rectangle 5, sa...

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Scheme 1: Guest addition/removal and reversible interconversion between supramolecular architectures.

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Scheme 2: Completive and incomplete self-sorting in presence of copper(I) and rhodium complex 3.

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Figure 2: Comparison of partial ¹H NMR spectra (400 MHz, CD₂Cl₂, 298 K) of (a) ligand 2; (b) ligand 1; (c) po...

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Figure 3: (a) UV–vis titration of rectangle 5 (2.98 μM) with DABCO (4); (b) several reversible cycles of inte...

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Scheme 3: The high selectivity for DABCO in the transformation.

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Figure 4: Partial spectra (400 MHz, CD₂Cl₂, 298 K) showing the reversible switching between rectangle and san...

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Letter

Published 21 Jun 2019

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